Chemfig Pfeile definieren

Dajb · Beitrag von **Dajb** » Do 14. Jun 2018, 20:04

Hallo liebe Fangemeinde, ich sitze gerade an meiner Bachelorarbeit und benötige diverse Pfeile für den Katalysezyklus. Jetzt bin ich bei meinen Recherchen auf diverse Seiten gestoßen die mein Problem zum Teil erklären. z.B. diese hier von Clemens (glaube er heißt hier "cgnieder"

) https://tex.stackexchange.com/questions ... in-chemfig. Aber leider brauch ich jetz einen Mix aus zwei definierten Pfeilen. Zum einen der auf der Internetseite und zum andern, diese gekrümmten Pfeile welche schon in der Chemifganleitung definiert sind.

hier das Minimalbeispiel

\documentclass[12pt]{article}
\usepackage[utf8]{inputenc}
\usepackage[T1]{fontenc}
\usepackage[ngerman]{babel}
\usepackage{chemfig}
\makeatletter
%Definition von Clemens auf der URL
\definearrow9{-X>}{%
    \CF@arrow@shift@nodes{#7}%
    \expandafter\draw\expandafter[\CF@arrow@current@style](\CF@arrow@start@node)--(\CF@arrow@end@node)node[midway](Xarrow@arctangent){};%
    \CF@ifempty{#8}
    {\def\CF@Xarrow@radius{0.333}}
    {\def\CF@Xarrow@radius{#8}}%
    \CF@ifempty{#9}%
    {\def\CF@Xarrow@absangle{60}}
    {\pgfmathsetmacro\CF@Xarrow@absangle{abs(#9)}}
    % Draw top arrow (start)
    \edef\CF@tmp@str{[\CF@ifempty{#1}{draw=none}{\unexpanded\expandafter{\CF@arrow@current@style}},-]}%
    \expandafter\draw\CF@tmp@str (Xarrow@arctangent)%
    arc[radius=\CF@compound@sep*\CF@current@arrow@length*\CF@Xarrow@radius,start angle=\CF@arrow@current@angle-90,delta angle=-\CF@Xarrow@absangle]node(Xarrow1@start){};
    % Draw bottom arrow (end)
    \edef\CF@tmp@str{[\CF@ifempty{#2}{draw=none}{\unexpanded\expandafter{\CF@arrow@current@style}},-CF]}%
    \expandafter\draw\CF@tmp@str (Xarrow@arctangent)%
    arc[radius=\CF@compound@sep*\CF@current@arrow@length*\CF@Xarrow@radius,%
    start angle=\CF@arrow@current@angle-90,%
    delta angle=\CF@Xarrow@absangle]%
    node(Xarrow1@end){};
    % Draw bottom arrow (start)
    \edef\CF@tmp@str{[\CF@ifempty{#4}{draw=none}{\unexpanded\expandafter{\CF@arrow@current@style}},-]}%
    \expandafter\draw\CF@tmp@str (Xarrow@arctangent)%
    arc[radius=\CF@compound@sep*\CF@current@arrow@length*\CF@Xarrow@radius,start angle=\CF@arrow@current@angle+90,delta angle=\CF@Xarrow@absangle]node(Xarrow2@start){};
    % Draw bottom arrow (end)
    \edef\CF@tmp@str{[\CF@ifempty{#5}{draw=none}{\unexpanded\expandafter{\CF@arrow@current@style}},-CF]}%
    \expandafter\draw\CF@tmp@str (Xarrow@arctangent)%
    arc[radius=\CF@compound@sep*\CF@current@arrow@length*\CF@Xarrow@radius,%
    start angle=\CF@arrow@current@angle+90,%
    delta angle=-\CF@Xarrow@absangle]%
    node(Xarrow2@end){};
    % Insert labels
    \pgfmathsetmacro\CF@tmp@stra{\CF@Xarrow@radius*cos(\CF@arrow@current@angle)<0?"-":"+"}%
    \pgfmathsetmacro\CF@tmp@strb{\CF@Xarrow@radius*cos(\CF@arrow@current@angle)<0?"+":"-"}%
    \ifdim\CF@Xarrow@radius pt>\z@
        \CF@arrow@display@label{#1}{0}\CF@tmp@stra{Xarrow1@start}{#2}{1}\CF@tmp@stra{Xarrow1@end}%
        \CF@arrow@display@label{#4}{0}\CF@tmp@strb{Xarrow2@start}{#5}{1}\CF@tmp@strb{Xarrow2@end}%
        \CF@arrow@display@label{#3}{0.5}\CF@tmp@stra\CF@arrow@start@node{}{}{}\CF@arrow@end@node%
        \CF@arrow@display@label{#6}{0.5}\CF@tmp@strb\CF@arrow@start@node{}{}{}\CF@arrow@end@node%
    \else
        \CF@arrow@display@label{#2}{0}\CF@tmp@stra{Xarrow1@start}{#1}{1}\CF@tmp@stra{Xarrow1@end}%
        \CF@arrow@display@label{#5}{0}\CF@tmp@strb{Xarrow2@start}{#4}{1}\CF@tmp@strb{Xarrow2@end}%
        \CF@arrow@display@label{#3}{0.5}\CF@tmp@stra\CF@arrow@start@node{}{}{}\CF@arrow@end@node%
        \CF@arrow@display@label{#6}{0.5}\CF@tmp@strb\CF@arrow@start@node{}{}{}\CF@arrow@end@node%
    \fi
}
%Definition der Chemfiganleitung auf S. 59
\definearrow1{s>}{%
    \ifx\@empty#1\@empty
    \expandafter\draw\expandafter[\CF@arrow@current@style,-CF](\CF@arrow@start@node)--(\CF@arrow@end@node);%
    \else
    \def\curvedarrow@style{shorten <=\CF@arrow@offset,shorten >=\CF@arrow@offset,}%
    \CF@expadd@tocs\curvedarrow@style\CF@arrow@current@style
    \expandafter\draw\expandafter[\curvedarrow@style,-CF](\CF@arrow@start@name)..controls#1..(\CF@arrow@end@name);
    \fi}
\makeatother
\usepackage{chemformula}
\setatomsep{1.5em}
\begin{document}
 \begin{equation*}
\schemestart
\chemfig{*6(-(-*6(-=-=-N(-[:30,2,,,dashed]Re?[a](-[2,1.5]Cl)(-[6,1.5]CO)(-[:-30,1.5]CO)(-[:30,1.5]CO))=))=N?[a,,dashed]-=-=)}
\arrow(.90--.180){s>[+(90:1.5) and +(180:1.5)]}[45,2]
\chemfig{*6(-(-*6(-=-=-N(-[:30,2,,,dashed]Re?[a](-[2,1.5]Cl)(-[6,1.5]CO)(-[:-30,1.5]CO)(-[:30,1.5]CO))=))=N?[a,,dashed]-=-=)}
\arrow{-X>[1][2][3][4][5][6][][0.333][60]}
\schemestop  
  \end{equation*}
\end{document}

Kann mir jemand diese beiden Pfeile in einem Pfeil definieren?
Diese Definition sprengt einfach meine Intelligenz

Ich bedanke mich außerordentlich im voraus